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Changing Concentration

Part of the Energy, Rates and Equilibrium section of Coddy's Chemistry journey. Lesson 28 of 35.

Fe³⁺(aq) + SCN⁻(aq) ⇌ FeSCN²⁺(aq): more SCN⁻ deepens the red (right); less Fe³⁺ fades it (left).

The reaction always moves to use up what was added or replace what was removed.

Adding a solid or a pure liquid does not shift it.

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Challenge

A few drops of potassium thiocyanate solution are added to this red mixture at equilibrium:

Fe3+(aq)+SCN−(aq)⇌FeSCN2+(aq)\mathrm{Fe^{3+}(aq)} + \mathrm{SCN^-(aq)} \rightleftharpoons \mathrm{FeSCN^{2+}(aq)}

Which way does the equilibrium shift?

Try it yourself

EquilibriumWhich way does it shift?

Fe3+(aq)SCN−(aq)FeSCN2+(aq)

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