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The Haber Process

Part of the Energy, Rates and Equilibrium section of Coddy's Chemistry journey. Lesson 31 of 35.

Haber: high pressure (about 200 atm200\ \mathrm{atm}) favours ammonia.

N2(g)+3H2(g)⇌2NH3(g)ΔH=−92 kJ\mathrm{N_2(g)} + 3\mathrm{H_2(g)} \rightleftharpoons 2\mathrm{NH_3(g)} \qquad \Delta H = -92\ \mathrm{kJ}

Low temperature favours ammonia but is too slow: about 450 ∘C450\ \mathrm{^{\circ}C} is the compromise.

The iron catalyst gives no shift and leaves K alone; equilibrium just comes sooner.

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Challenge

A Haber plant switches to a new, more active iron catalyst:

N2(g)+3H2(g)⇌2NH3(g)ΔH=−92 kJ\mathrm{N_2(g)} + 3\mathrm{H_2(g)} \rightleftharpoons 2\mathrm{NH_3(g)} \qquad \Delta H = -92\ \mathrm{kJ}

Which way does the equilibrium shift, and what happens to K?

Try it yourself

EquilibriumWhich way does it shift?

N2(g)3 H2(g)2 NH3(g)

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