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Giant Covalent Structures

Part of the Structure and Bonding section of Coddy's Chemistry journey. Lesson 36 of 49.

In silicon dioxide, SiO₂ (quartz, sand), each Si is bonded to four O and each O to two Si, through the whole crystal. SiO₂ is a ratio, not a molecule.

A giant covalent structure: melting means breaking covalent bonds, so the melting point is very high (quartz about 1700 °C). Hard, insoluble, no conduction.

Each Si-O bond is polar covalent: oxygen is far more electronegative than silicon.

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Challenge

Quartz, the mineral of sand and glass, is silicon dioxide: every silicon atom is bonded to four oxygen atoms. Describe one Si-O bond: what kind of bond it is, and which atom carries the negative end.

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Bond typeDescribe the bond Si–O
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