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When Dipoles Cancel

Part of the Structure and Bonding section of Coddy's Chemistry journey. Lesson 26 of 49.

Identical polar bonds spread evenly around the central atom cancel: the molecule is non-polar.

CO₂, BF₃, BH₃, CH₄ and CCl₄ are non-polar. Different atoms around the centre, or lone pairs that bend the shape, break the balance (CHCl₃, H₂O).

Boron trifluoride and tetrachloromethane, symmetric, beside trichloromethane, where one chlorine is replaced by hydrogen

Symmetric molecules cancel their dipoles; replace one atom and they no longer do

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Challenge

Boron trifluoride, BF₃, has three strongly polar B-F bonds. What shape is it, and is the molecule polar?

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Shape viewerDescribe the molecule BF3
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